Highly Tunable Nanostructures in a Doubly pH‐Responsive Pentablock Terpolymer in Solution and in Thin Films

Jung F, Schart M, Bührend L, Meidinger E, Kang J, Niebuur B, Ariaee S, Molodenskiy D, Posselt D, Amenitsch H, Tsitsilianis C, Papadakis C, Advanced Functional Materials 31(32):2102905 (2021) DOI

SASDPG8 – Solution of 0.1 wt% pentablock terpolymer (M18D170V209D170M18) in water at pH 2.6

M18D170V209D170M18
MWexperimental 19 kDa
MWexpected 1 kDa
log I(s) 2.06×10-2 2.06×10-3 2.06×10-4 2.06×10-5
M18D170V209D170M18 small angle scattering data  s, nm-1
ln I(s)
M18D170V209D170M18 Guinier plot ln 2.06×10-2 Rg: 8.7 nm 0 (8.7 nm)-2 s2
(sRg)2I(s)/I(0)
M18D170V209D170M18 Kratky plot 1.104 0 √3 sRg

Data validation

There are no models related to this curve.

Synchrotron SAXS data from solutions of Solution of 0.1 wt% pentablock terpolymer (M18D170V209D170M18) in water at pH 2.6 in H20, pH 2.6 were collected on the EMBL P12 beam line at the PETRA III storage ring (DESY; Hamburg, Germany) using a Pilatus 6M detector at a sample-detector distance of 3 m and at a wavelength of λ = 0.123 nm (I(s) vs s, where s = 4πsinθ/λ, and 2θ is the scattering angle). One solute concentration of 1.00 mg/ml was measured at 20°C. 80 successive 0.050 second frames were collected. The data were normalized to the intensity of the transmitted beam and radially averaged; the scattering of the solvent-blank was subtracted.

M18D170V209D170M18 (MDV)
Mol. type   Other
Olig. state   Monomer
Mon. MW   1 kDa